Study hints that ancient Earth made its own water — geologically

A new study is helping to answer a longstanding question that has recently moved to the forefront of earth science: Did our planet make its own water through geologic processes, or did water come to us via icy comets from the far reaches of the solar system?

The answer is likely “both,” according to researchers at The Ohio State University– and the same amount of water that currently fills the Pacific Ocean could be buried deep inside the planet right now.

At the American Geophysical Union (AGU) meeting on Wednesday, Dec. 17, they report the discovery of a previously unknown geochemical pathway by which the Earth can sequester water in its interior for billions of years and still release small amounts to the surface via plate tectonics, feeding our oceans from within.

In trying to understand the formation of the early Earth, some researchers have suggested that the planet was dry and inhospitable to life until icy comets pelted the earth and deposited water on the surface.

Wendy Panero, associate professor of earth sciences at Ohio State, and doctoral student Jeff Pigott are pursuing a different hypothesis: that Earth was formed with entire oceans of water in its interior, and has been continuously supplying water to the surface via plate tectonics ever since.

Researchers have long accepted that the mantle contains some water, but how much water is a mystery. And, if some geological mechanism has been supplying water to the surface all this time, wouldn’t the mantle have run out of water by now?

Because there’s no way to directly study deep mantle rocks, Panero and Pigott are probing the question with high-pressure physics experiments and computer calculations.

“When we look into the origins of water on Earth, what we’re really asking is, why are we so different than all the other planets?” Panero said. “In this solar system, Earth is unique because we have liquid water on the surface. We’re also the only planet with active plate tectonics. Maybe this water in the mantle is key to plate tectonics, and that’s part of what makes Earth habitable.”

Central to the study is the idea that rocks that appear dry to the human eye can actually contain water–in the form of hydrogen atoms trapped inside natural voids and crystal defects. Oxygen is plentiful in minerals, so when a mineral contains some hydrogen, certain chemical reactions can free the hydrogen to bond with the oxygen and make water.

Stray atoms of hydrogen could make up only a tiny fraction of mantle rock, the researchers explained. Given that the mantle is more than 80 percent of the planet’s total volume, however, those stray atoms add up to a lot of potential water.

In a lab at Ohio State, the researchers compress different minerals that are common to the mantle and subject them to high pressures and temperatures using a diamond anvil cell–a device that squeezes a tiny sample of material between two diamonds and heats it with a laser–to simulate conditions in the deep Earth. They examine how the minerals’ crystal structures change as they are compressed, and use that information to gauge the minerals’ relative capacities for storing hydrogen. Then, they extend their experimental results using computer calculations to uncover the geochemical processes that would enable these minerals to rise through the mantle to the surface–a necessary condition for water to escape into the oceans.

In a paper now submitted to a peer-reviewed academic journal, they reported their recent tests of the mineral bridgmanite, a high-pressure form of olivine. While bridgmanite is the most abundant mineral in the lower mantle, they found that it contains too little hydrogen to play an important role in Earth’s water supply.

Another research group recently found that ringwoodite, another form of olivine, does contain enough hydrogen to make it a good candidate for deep-earth water storage. So Panero and Pigott focused their study on the depth where ringwoodite is found–a place 325-500 miles below the surface that researchers call the “transition zone”–as the most likely region that can hold a planet’s worth of water. From there, the same convection of mantle rock that produces plate tectonics could carry the water to the surface.

One problem: If all the water in ringwoodite is continually drained to the surface via plate tectonics, how could the planet hold any in reserve?

For the research presented at AGU, Panero and Pigott performed new computer calculations of the geochemistry in the lowest portion of the mantle, some 500 miles deep and more. There, another mineral, garnet, emerged as a likely water-carrier–a go-between that could deliver some of the water from ringwoodite down into the otherwise dry lower mantle.

If this scenario is accurate, the Earth may today hold half as much water in its depths as is currently flowing in oceans on the surface, Panero said–an amount that would approximately equal the volume of the Pacific Ocean. This water is continuously cycled through the transition zone as a result of plate tectonics.

“One way to look at this research is that we’re putting constraints on the amount of water that could be down there,” Pigott added.

Panero called the complex relationship between plate tectonics and surface water “one of the great mysteries in the geosciences.” But this new study supports researchers’ growing suspicion that mantle convection somehow regulates the amount of water in the oceans. It also vastly expands the timeline for Earth’s water cycle.

“If all of the Earth’s water is on the surface, that gives us one interpretation of the water cycle, where we can think of water cycling from oceans into the atmosphere and into the groundwater over millions of years,” she said. “But if mantle circulation is also part of the water cycle, the total cycle time for our planet’s water has to be billions of years.”

North Atlantic signalled Ice Age thaw 1,000 years before it happened, reveals new research

The Atlantic Ocean at mid-depths may have given out early warning signals – 1,000 years in advance – that the last Ice Age was going to end, scientists report today in the journal Paleoceanography.

Scientists had previously known that at the end of the last Ice Age, around 14,700 years ago, major changes occurred to the Atlantic Ocean in a period known as the Bolling-Allerod interval. During this period, as glaciers melted and the Earth warmed, the currents of the Atlantic Ocean at its deepest levels changed direction.

The researchers have analysed the chemistry of 24 ancient coral fossils from the North Atlantic Ocean to learn more about the circulation of its waters during the last Ice Age. They found that the corals recorded a high variability in the currents of the Atlantic Ocean at mid-depths, around 2km below the surface, up to 1,000 years prior to the Bolling-Allerod interval. The team suggests that these changes may have been an early warning signal that the world was poised to switch from its glacial state to the warmer world we know today, and that the changes happened first at mid-depths.

The study was carried out by researchers from Imperial College London in conjunction with academics from the Scottish Marine Institute, the University of Bristol and Caltech Division of Geology and Planetary Sciences.

Dr David Wilson, from the Department of Earth Science and Engineering at Imperial College London, said: “The world’s oceans have always been an important barometer when it comes to changes in our planet. Excitingly, the coral fossils we’ve studied are showing us that the North Atlantic Ocean at mid-depths was undergoing changes up to 1,000 years earlier than we had expected. The tantalising prospect is that this high variability may have been a signal that the last Ice Age was about to end.”

The fossil corals analysed by the team come from a species called Desmophyllum dianthus, which are often around 5cm in diameter and look like budding flowers. They typically only live for 100 years, giving the team a rare insight into what was happening to the ocean’s currents during this relatively brief time. Thousands of years ago they grew on the New England Seamounts, which are a chain of undersea mountains approximately 1000km off the east coast of the US, located at mid-depths 2km beneath the surface. This underwater area is important for understanding the North Atlantic’s currents.

While some of the corals analysed by the team come from historical collections, most have been collected by researchers from previous expeditions in 2003 and 2005 to the New England Seamounts. The researchers used deep sea robotic submergence vehicles called Hercules and Alvin to collect the ancient coral fossils.

These ancient coral fossils accumulated rare earth elements from seawater, including neodymium, which leached from rocks on land into the Atlantic Ocean and circulated in its currents, eventually ending up in the coral skeletons. Neodymium isotopes in different regions of the world have specific signatures, created by radioactive decay over billions of years. The scientists studied the chemistry of the coral fossils to determine where the neodymium isotopes had come from, giving them a glimpse into the circulation of the Atlantic Ocean at the end of the Ice Age.

Since the world’s oceans are connected by currents, the next step will see the team integrating the evidence they gathered from the North Atlantic Ocean into a picture of global changes in the mid-depths of oceans around the world. In particular, the team is interested in exploring how the Southern Ocean around Antarctica changed around the same time by analysing neodymium isotopes in a collection of Southern Ocean corals.

Massive study provides first detailed look at how Greenland’s ice is vanishing

The surface of the Greenland Ice Sheet. A new study uses NASA data to provide the first detailed reconstruction of how the ice sheet and its many glaciers are changing. The research was led by University at Buffalo geologist Beata Csatho. -  Beata Csatho
The surface of the Greenland Ice Sheet. A new study uses NASA data to provide the first detailed reconstruction of how the ice sheet and its many glaciers are changing. The research was led by University at Buffalo geologist Beata Csatho. – Beata Csatho

The Greenland Ice Sheet is the second-largest body of ice on Earth. It covers an area about five times the size of New York State and Kansas combined, and if it melts completely, oceans could rise by 20 feet. Coastal communities from Florida to Bangladesh would suffer extensive damage.

Now, a new study is revealing just how little we understand this northern behemoth.

Led by geophysicist Beata Csatho, PhD, an associate professor of geology at the University at Buffalo, the research provides what the authors think is the first comprehensive picture of how Greenland’s ice is vanishing. It suggests that current ice sheet modeling studies are too simplistic to accurately predict the future contributions of the entire Greenland Ice Sheet to sea level rise, and that Greenland may lose ice more rapidly in the near future than previously thought.

“The great importance of our data is that for the first time, we have a comprehensive picture of how all of Greenland’s glaciers have changed over the past decade,” Csatho says.

“This information is crucial for developing and validating numerical models that predict how the ice sheet may change and contribute to global sea level over the next few hundred years,” says Cornelis J. van der Veen, PhD, professor in the Department of Geography at the University of Kansas, who played a key role in interpreting glaciological changes.

The project was a massive undertaking, using satellite and aerial data from NASA’s ICESat spacecraft and Operation IceBridge field campaign to reconstruct how the height of the Greenland Ice Sheet changed at nearly 100,000 locations from 1993 to 2012.

Ice loss takes place in a complex manner, with the ice sheet both melting and calving ice into the ocean.
The study had two major findings:

  • First, the scientists were able to provide new estimates of annual ice loss at high spatial resolution (see below).

  • Second, the research revealed that current models fail to accurately capture how the entire Greenland Ice Sheet is changing and contributing to rising oceans.

The second point is crucial to climate change modelers.

Today’s simulations use the activity of four well-studied glaciers — Jakobshavn, Helheim, Kangerlussuaq and Petermann — to forecast how the entire ice sheet will dump ice into the oceans.

But the new research shows that activity at these four locations may not be representative of what is happening with glaciers across the ice sheet. In fact, glaciers undergo patterns of thinning and thickening that current climate change simulations fail to address, Csatho says.

“There are 242 outlet glaciers wider than 1.5 km on the Greenland Ice Sheet, and what we see is that their behavior is complex in space and time,” Csatho says. “The local climate and geological conditions, the local hydrology — all of these factors have an effect. The current models do not address this complexity.”

The team identified areas of rapid shrinkage in southeast Greenland that today’s models don’t acknowledge. This leads Csatho to believe that the ice sheet could lose ice faster in the future than today’s simulations would suggest.

The results will be published on Dec. 15 in the Proceedings of the National Academy of Sciences, and the study and all information in this press release are embargoed until 3 p.m. Eastern Time that day.

Photos, data visualizations and video are available by contacting Charlotte Hsu at the University at Buffalo at

How much ice is the Greenland Ice Sheet losing?

To analyze how the height of the ice sheet was changing, Csatho and UB research professor and photogrammetrist Anton Schenk, PhD, developed a computational technique called Surface Elevation Reconstruction And Change detection to fuse together data from NASA satellite and aerial missions.

The analysis found that the Greenland Ice Sheet lost about 243 metric gigatons of ice annually — equivalent to about 277 cubic kilometers of ice per year — from 2003-09, the period for which the team had the most comprehensive data. This loss is estimated to have added about 0.68 millimeters of water to the oceans annually.

The figures are averages, and ice loss varied from year to year, and from region to region.

Why are today’s projections of sea level rise flawed, and how can we fix them?

Glaciers don’t just gradually lose mass when the temperature rises. That’s one reason it’s difficult to predict their response to global warming.

In the study, scientists found that some of Greenland’s glaciers thickened even when the temperature rose. Others exhibited accelerated thinning. Some displayed both thinning and thickening, with sudden reversals.

As a step toward building better models of sea level rise, the research team divided Greenland’s 242 glaciers into 7 major groups based on their behavior from 2003-09.

“Understanding the groupings will help us pick out examples of glaciers that are representative of the whole,” Csatho says. “We can then use data from these representative glaciers in models to provide a more complete picture of what is happening.”

In a new project, she and colleagues are investigating why different glaciers respond differently to warming. Factors could include the temperature of the surrounding ocean; the level of friction between a glacier and the bedrock below; the amount of water under a glacier; and the geometry of the fjord.

“The physics of these processes are not well understood,” Csatho says.

The NASA missions: A colossal undertaking

The study combined data from various NASA missions, including:

  • NASA’s Ice, Cloud and Land Elevation Satellite (ICESat), which measured the ice sheet’s elevation multiple times a year at each of the nearly 100,000 locations from 2003-09.

  • NASA’s, massive aerial survey that employs highly specialized research aircrafts to collect data at less frequent intervals than ICESat. These missions began measuring the Greenland Ice Sheet’s elevation in 1993. Operation IceBridge was started in 2009 to bridge the time between ICESat-1 and ICESat-2, and will continue until at least 2017, when NASA’s next generation ICESat-2 satellite is expected to come online.

Csatho says the new study shows why careful monitoring is critical: Given the complex nature of glacier behavior, good data is crucial to building better models.


Besides Csatho, Schenk and van der Veen, the project included additional researchers from the University at Buffalo, Utrecht University in The Netherlands, the Technical University of Denmark and Florida Atlantic University.

Research links soil mineral surfaces to key atmospheric processes

Pictured are, from left, are David Bish, Melissa Donaldson and Jonathan Raff. -  Indiana University
Pictured are, from left, are David Bish, Melissa Donaldson and Jonathan Raff. – Indiana University

Research by Indiana University scientists finds that soil may be a significant and underappreciated source of nitrous acid, a chemical that plays a pivotal role in atmospheric processes such as the formation of smog and determining the lifetime of greenhouse gases.

The study shows for the first time that the surface acidity of common minerals found in soil determines whether the gas nitrous acid will be released into the atmosphere. The finding could contribute to improved models for understanding and controlling air pollution, a significant public health concern.

“We find that the surfaces of minerals in the soil can be much more acidic than the overall pH of the soil would suggest,” said Jonathan Raff, assistant professor in the School of Public and Environmental Affairs and Department of Chemistry. “It’s the acidity of the soil minerals that acts as a knob or a control lever, and that determines whether nitrous acid outgasses from soil or remains as nitrite.”

The article, “Soil surface acidity plays a determining role in the atmospheric-terrestrial exchange of nitrous acid,” will be published this week in the journal Proceedings of the National Academy of Sciences. Melissa A. Donaldson, a Ph.D. student in the School of Public and Environmental Affairs, is the lead author. Co-authors are Raff and David L. Bish, the Haydn Murray Chair of Applied Clay Mineralogy in the Department of Geological Sciences.

Nitrous acid, or HONO, plays a key role in regulating atmospheric processes. Sunlight causes it to break down into nitric oxide and the hydroxyl radical, OH. The latter controls the atmospheric lifetime of gases important to air quality and climate change and initiates the chemistry leading to the formation of ground-level ozone, a primary component of smog.

Scientists have known about the nitrous acid’s role in air pollution for 40 years, but they haven’t fully understood how it is produced and destroyed or how it interacts with other substances, because HONO is unstable and difficult to measure.

“Only in the last 10 years have we had the technology to study nitrous acid under environmentally relevant conditions,” Raff said.

Recent studies have shown nitrous acid to be emitted from soil in many locations. But this was unexpected because, according to basic chemistry, the reactions that release nitrous acid should take place only in extremely acidic soils, typically found in rain forests or the taiga of North America and Eurasia.

The standard method to determine the acidity of soil is to mix bulk soil with water and measure the overall pH. But the IU researchers show that the crucial factor is not overall pH but the acidity at the surface of soil minerals, especially iron oxides and aluminum oxides. At the molecular level, the water adsorbed directly to these minerals is unusually acidic and facilitates the conversion of nitrite in the soil to nitrous acid, which then volatilizes.

“With the traditional approach of calculating soil pH, we were severely underestimating nitrous acid emissions from soil,” Raff said. “I think the source is going to turn out to be more important than was previously imagined.”

The research was carried out using soil from a farm field near Columbus, Ind. But aluminum and iron oxides are ubiquitous in soil, and the researchers say the results suggest that about 70 percent of Earth’s soils could be sources of nitrous acid.

Ultimately, the research will contribute to a better understanding of how nitrous acid is produced and how it affects atmospheric processes. That in turn will improve the computer models used by the U.S. Environmental Protection Agency and other regulatory agencies to control air pollution, which the World Health Organization estimates contributes to 7 million premature deaths annually.

“With improved models, policymakers can make better judgments about the costs and benefits of regulations,” Raff said. “If we don’t get the chemistry right, we’re not going to get the right answers to our policy questions regarding air pollution.”

Scientists observe the Earth grow a new layer under an Icelandic volcano

New research into an Icelandic eruption has shed light on how the Earth’s crust forms, according to a paper published today in Nature.

When the Bárðarbunga volcano, which is buried beneath Iceland’s Vatnajökull ice cap, reawakened in August 2014, scientists had a rare opportunity to monitor how the magma flowed through cracks in the rock away from the volcano. The molten rock forms vertical sheet-like features known as dykes, which force the surrounding rock apart.

Study co-author Professor Andy Hooper from the Centre for Observation and Modelling of Earthquakes, volcanoes and Tectonics (COMET) at the University of Leeds explained: “New crust forms where two tectonic plates are moving away from each other. Mostly this happens beneath the oceans, where it is difficult to observe.

“However, in Iceland this happens beneath dry land. The events leading to the eruption in August 2014 are the first time that such a rifting episode has occurred there and been observed with modern tools, like GPS and satellite radar.”

Although it has a long history of eruptions, Bárðarbunga has been increasingly restless since 2005. There was a particularly dynamic period in August and September this year, when more than 22,000 earthquakes were recorded in or around the volcano in just four weeks, due to stress being released as magma forced its way through the rock.

Using GPS and satellite measurements, the team were able to track the path of the magma for over 45km before it reached a point where it began to erupt, and continues to do so to this day. The rate of dyke propagation was variable and slowed as the magma reached natural barriers, which were overcome by the build-up of pressure, creating a new segment.

The dyke grows in segments, breaking through from one to the next by the build up of pressure. This explains how focused upwelling of magma under central volcanoes is effectively redistributed over large distances to create new upper crust at divergent plate boundaries, the authors conclude.

As well as the dyke, the team found ‘ice cauldrons’ – shallow depressions in the ice with circular crevasses, where the base of the glacier had been melted by magma. In addition, radar measurements showed that the ice inside Bárðarbunga’s crater had sunk by 16m, as the volcano floor collapsed.

COMET PhD student Karsten Spaans from the University of Leeds, a co-author of the study, added: “Using radar measurements from space, we can form an image of caldera movement occurring in one day. Usually we expect to see just noise in the image, but we were amazed to see up to 55cm of subsidence.”

Like other liquids, magma flows along the path of least resistance, which explains why the dyke at Bárðarbunga changed direction as it progressed. Magma flow was influenced mostly by the lie of the land to start with, but as it moved away from the steeper slopes, the influence of plate movements became more important.

Summarising the findings, Professor Hooper said: “Our observations of this event showed that the magma injected into the crust took an incredibly roundabout path and proceeded in fits and starts.

“Initially we were surprised at this complexity, but it turns out we can explain all the twists and turns with a relatively simple model, which considers just the pressure of rock and ice above, and the pull exerted by the plates moving apart.”

The paper ‘Segmented lateral dyke growth in a rifting event at Bárðarbunga volcanic system, Iceland’ is published in Nature on 15 December 2014.

The research leading to these results has received funding from the European Community’s Seventh Framework Programme under Grant Agreement No. 308377 (Project FUTUREVOLC)

New study measures methane emissions from natural gas production and offers insights into 2 large sources

A team of researchers from the Cockrell School of Engineering at The University of Texas at Austin and environmental testing firm URS reports that a small subset of natural gas wells are responsible for the majority of methane emissions from two major sources — liquid unloadings and pneumatic controller equipment — at natural gas production sites.

With natural gas production in the United States expected to continue to increase during the next few decades, there is a need for a better understanding of methane emissions during natural gas production. The study team believes this research, published Dec. 9 in Environmental Science & Technology, will help to provide a clearer picture of methane emissions from natural gas production sites.

The UT Austin-led field study closely examined two major sources of methane emissions — liquid unloadings and pneumatic controller equipment — at well pad sites across the United States. Researchers found that 19 percent of the pneumatic devices accounted for 95 percent of the emissions from pneumatic devices, and 20 percent of the wells with unloading emissions that vent to the atmosphere accounted for 65 percent to 83 percent of those emissions.

“To put this in perspective, over the past several decades, 10 percent of the cars on the road have been responsible for the majority of automotive exhaust pollution,” said David Allen, chemical engineering professor at the Cockrell School and principal investigator for the study. “Similarly, a small group of sources within these two categories are responsible for the vast majority of pneumatic and unloading emissions at natural gas production sites.”

Additionally, for pneumatic devices, the study confirmed regional differences in methane emissions first reported by the study team in 2013. The researchers found that methane emissions from pneumatic devices were highest in the Gulf Coast and lowest in the Rocky Mountains.

The study is the second phase of the team’s 2013 study, which included some of the first measurements for methane emissions taken directly at hydraulically fractured well sites. Both phases of the study involved a partnership between the Environmental Defense Fund, participating energy companies, an independent Scientific Advisory Panel and the UT Austin study team.

The unprecedented access to natural gas production facilities and equipment allowed researchers to acquire direct measurements of methane emissions.

Study and Findings on Pneumatic Devices

Pneumatic devices, which use gas pressure to control the opening and closing of valves, emit gas as they operate. These emissions are estimated to be among the larger sources of methane emissions from the natural gas supply chain. The Environmental Protection Agency reports that 477,606 pneumatic (gas actuated) devices are in use at natural gas production sites throughout the U.S.

“Our team’s previous work established that pneumatics are a major contributor to emissions,” Allen said. “Our goal here was to measure a more diverse population of wells to characterize the features of high-emitting pneumatic controllers.”

The research team measured emissions from 377 gas actuated (pneumatic) controllers at natural gas production sites and a small number of oil production sites throughout the U.S.

The researchers sampled all identifiable pneumatic controller devices at each well site, a more comprehensive approach than the random sampling previously conducted. The average methane emissions per pneumatic controller reported in this study are 17 percent higher than the average emissions per pneumatic controller in the 2012 EPA greenhouse gas national emission inventory (released in 2014), but the average from the study is dominated by a small subpopulation of the controllers. Specifically, 19 percent of controllers, with measured emission rates in excess of 6 standard cubic feet per hour (scf/h), accounted for 95 percent of emissions.

The high-emitting pneumatic devices are a combination of devices that are not operating as designed, are used in applications that cause them to release gas frequently or are designed to emit continuously at a high rate.

The researchers also observed regional differences in methane emission levels, with the lowest emissions per device measured in the Rocky Mountains and the highest emissions in the Gulf Coast, similar to the earlier 2013 study. At least some of the regional differences in emission rates can be attributed to the difference in controller type (continuous vent vs. intermittent vent) among regions.

Study and Findings on Liquid Unloadings

After observing variable emissions for liquid unloadings for a limited group of well types in the 2013 study, the research team made more extensive measurements and confirmed that a majority of emissions come from a small fraction of wells that vent frequently. Although it is not surprising to see some correlation between frequency of unloadings and higher annual emissions, the study’s findings indicate that wells with a high frequency of unloadings have annual emissions that are 10 or more times as great as wells that unload less frequently.

The team’s field study, which measured emissions from unloadings from wells at 107 natural gas production wells throughout the U.S., represents the most extensive measurement of emissions associated with liquid unloadings in scientific literature thus far.

A liquid unloading is one method used to clear wells of accumulated liquids to increase production. Because older wells typically produce less gas as they near the end of their life cycle, liquid unloadings happen more often in those wells than in newer wells. The team found a statistical correlation between the age of wells and the frequency of liquid unloadings. The researchers found that the key identifier for high-emitting wells is how many times the well unloads in a given year.

Because liquid unloadings can employ a variety of liquid lifting mechanisms, the study results also reflect differences in liquid unloadings emissions between wells that use two different mechanisms (wells with plunger lifts and wells without plunger lifts). Emissions for unloading events for wells without plunger lifts averaged 21,000 scf (standard cubic feet) to 35,000 scf. For wells with plunger lifts that vent to the atmosphere, emissions averaged 1,000 scf to 10,000 scf of methane per event. Although the emissions per event were higher for wells without plunger lifts, these wells had, on average, fewer events than wells with plunger lifts. Wells without plunger lifts averaged fewer than 10 unloading events per year, and wells with plunger lifts averaged more than 200 events per year.Overall, wells with plunger lifts were estimated to account for 70 percent of emissions from unloadings nationally.

Additionally, researchers found that the Rocky Mountain region, with its large number of wells with a high frequency of unloadings that vent to the atmosphere, accounts for about half of overall emissions from liquid unloadings.

The study team hopes its measurements of liquid unloadings and pneumatic devices will provide a clearer picture of methane emissions from natural gas well sites and about the relationship between well characteristics and emissions.

The study was a cooperative effort involving experts from the Environmental Defense Fund, Anadarko Petroleum Corporation, BG Group PLC, Chevron, ConocoPhillips, Encana Oil & Gas (USA) Inc., Pioneer Natural Resources Company, SWEPI LP (Shell), Statoil, Southwestern Energy and XTO Energy, a subsidiary of ExxonMobil.

The University of Texas at Austin is committed to transparency and disclosure of all potential conflicts of interest of its researchers. Lead researcher David Allen serves as chair of the Environmental Protection Agency’s Science Advisory Board and in this role is a paid Special Governmental Employee. He is also a journal editor for the American Chemical Society and has served as a consultant for multiple companies, including Eastern Research Group, ExxonMobil and the Research Triangle Institute. He has worked on other research projects funded by a variety of governmental, nonprofit and private sector sources including the National Science Foundation, the Environmental Protection Agency, the Texas Commission on Environmental Quality, the American Petroleum Institute and an air monitoring and surveillance project that was ordered by the U.S. District Court for the Southern District of Texas. Adam Pacsi and Daniel Zavala-Araiza, who were graduate students at The University of Texas at the time this work was done, have accepted positions at Chevron Energy Technology Company and the Environmental Defense Fund, respectively.

Financial support for this work was provided by the Environmental Defense Fund (EDF), Anadarko Petroleum Corporation, BG Group PLC, Chevron, ConocoPhillips, Encana Oil & Gas (USA) Inc., Pioneer Natural Resources Company, SWEPI LP (Shell), Statoil, Southwestern Energy and XTO Energy, a subsidiary of ExxonMobil.

Major funding for the EDF’s 30-month methane research series, including their portion of the University of Texas study, is provided for by the following individuals and foundations: Fiona and Stan Druckenmiller, the Heising-Simons Foundation, Bill and Susan Oberndorf, Betsy and Sam Reeves, the Robertson Foundation, TomKat Charitable Trust and the Walton Family Foundation.

No laughing matter: Nitrous oxide rose at end of last ice age

Researchers measured increases in atmospheric nitrous oxide concentrations about 16,000 to 10,000 years ago using ice from Taylor Glacier in Antarctica. -  Adrian Schilt
Researchers measured increases in atmospheric nitrous oxide concentrations about 16,000 to 10,000 years ago using ice from Taylor Glacier in Antarctica. – Adrian Schilt

Nitrous oxide (N2O) is an important greenhouse gas that doesn’t receive as much notoriety as carbon dioxide or methane, but a new study confirms that atmospheric levels of N2O rose significantly as the Earth came out of the last ice age and addresses the cause.

An international team of scientists analyzed air extracted from bubbles enclosed in ancient polar ice from Taylor Glacier in Antarctica, allowing for the reconstruction of the past atmospheric composition. The analysis documented a 30 percent increase in atmospheric nitrous oxide concentrations from 16,000 years ago to 10,000 years ago. This rise in N2O was caused by changes in environmental conditions in the ocean and on land, scientists say, and contributed to the warming at the end of the ice age and the melting of large ice sheets that then existed.

The findings add an important new element to studies of how Earth may respond to a warming climate in the future. Results of the study, which was funded by the U.S. National Science Foundation and the Swiss National Science Foundation, are being published this week in the journal Nature.

“We found that marine and terrestrial sources contributed about equally to the overall increase of nitrous oxide concentrations and generally evolved in parallel at the end of the last ice age,” said lead author Adrian Schilt, who did much of the work as a post-doctoral researcher at Oregon State University. Schilt then continued to work on the study at the Oeschger Centre for Climate Change Research at the University of Bern in Switzerland.

“The end of the last ice age represents a partial analog to modern warming and allows us to study the response of natural nitrous oxide emissions to changing environmental conditions,” Schilt added. “This will allow us to better understand what might happen in the future.”

Nitrous oxide is perhaps best known as laughing gas, but it is also produced by microbes on land and in the ocean in processes that occur naturally, but can be enhanced by human activity. Marine nitrous oxide production is linked closely to low oxygen conditions in the upper ocean and global warming is predicted to intensify the low-oxygen zones in many of the world’s ocean basins. N2O also destroys ozone in the stratosphere.

“Warming makes terrestrial microbes produce more nitrous oxide,” noted co-author Edward Brook, an Oregon State paleoclimatologist whose research team included Schilt. “Greenhouse gases go up and down over time, and we’d like to know more about why that happens and how it affects climate.”

Nitrous oxide is among the most difficult greenhouse gases to study in attempting to reconstruct the Earth’s climate history through ice core analysis. The specific technique that the Oregon State research team used requires large samples of pristine ice that date back to the desired time of study – in this case, between about 16,000 and 10,000 years ago.

The unusual way in which Taylor Glacier is configured allowed the scientists to extract ice samples from the surface of the glacier instead of drilling deep in the polar ice cap because older ice is transported upward near the glacier margins, said Brook, a professor in Oregon State’s College of Earth, Ocean, and Atmospheric Sciences.

The scientists were able to discern the contributions of marine and terrestrial nitrous oxide through analysis of isotopic ratios, which fingerprint the different sources of N2O in the atmosphere.

“The scientific community knew roughly what the N2O concentration trends were prior to this study,” Brook said, “but these findings confirm that and provide more exact details about changes in sources. As nitrous oxide in the atmosphere continues to increase – along with carbon dioxide and methane – we now will be able to more accurately assess where those contributions are coming from and the rate of the increase.”

Atmospheric N2O was roughly 200 parts per billion at the peak of the ice age about 20,000 years ago then rose to 260 ppb by 10,000 years ago. As of 2014, atmospheric N2Owas measured at about 327 ppb, an increase attributed primarily to agricultural influences.

Although the N2O increase at the end of the last ice age was almost equally attributable to marine and terrestrial sources, the scientists say, there were some differences.

“Our data showed that terrestrial emissions changed faster than marine emissions, which was highlighted by a fast increase of emissions on land that preceded the increase in marine emissions,” Schilt pointed out. “It appears to be a direct response to a rapid temperature change between 15,000 and 14,000 years ago.”

That finding underscores the complexity of analyzing how Earth responds to changing conditions that have to account for marine and terrestrial influences; natural variability; the influence of different greenhouse gases; and a host of other factors, Brook said.

“Natural sources of N2O are predicted to increase in the future and this study will help up test predictions on how the Earth will respond,” Brook said.

Technology-dependent emissions of gas extraction in the US

The KIT measurement instrument on board of a minivan directly measures atmospheric emissions on site with a high temporal resolution. -  Photo: F. Geiger/KIT
The KIT measurement instrument on board of a minivan directly measures atmospheric emissions on site with a high temporal resolution. – Photo: F. Geiger/KIT

Not all boreholes are the same. Scientists of the Karlsruhe Institute of Technology (KIT) used mobile measurement equipment to analyze gaseous compounds emitted by the extraction of oil and natural gas in the USA. For the first time, organic pollutants emitted during a fracking process were measured at a high temporal resolution. The highest values measured exceeded typical mean values in urban air by a factor of one thousand, as was reported in ACP journal. (DOI 10.5194/acp-14-10977-2014)

Emission of trace gases by oil and gas fields was studied by the KIT researchers in the USA (Utah and Colorado) together with US institutes. Background concentrations and the waste gas plumes of single extraction plants and fracking facilities were analyzed. The air quality measurements of several weeks duration took place under the “Uintah Basin Winter Ozone Study” coordinated by the National Oceanic and Atmospheric Administration (NOAA).

The KIT measurements focused on health-damaging aromatic hydrocarbons in air, such as carcinogenic benzene. Maximum concentrations were determined in the waste gas plumes of boreholes. Some extraction plants emitted up to about a hundred times more benzene than others. The highest values of some milligrams of benzene per cubic meter air were measured downstream of an open fracking facility, where returning drilling fluid is stored in open tanks and basins. Much better results were reached by oil and gas extraction plants and plants with closed production processes. In Germany, benzene concentration at the workplace is subject to strict limits: The Federal Emission Control Ordinance gives an annual benzene limit of five micrograms per cubic meter for the protection of human health, which is smaller than the values now measured at the open fracking facility in the US by a factor of about one thousand. The researchers published the results measured in the journal Atmospheric Chemistry and Physics ACP.

“Characteristic emissions of trace gases are encountered everywhere. These are symptomatic of gas and gas extraction. But the values measured for different technologies differ considerably,” Felix Geiger of the Institute of Meteorology and Climate Research (IMK) of KIT explains. He is one of the first authors of the study. By means of closed collection tanks and so-called vapor capture systems, for instance, the gases released during operation can be collected and reduced significantly.

“The gas fields in the sparsely populated areas of North America are a good showcase for estimating the range of impacts of different extraction and fracking technologies,” explains Professor Johannes Orphal, Head of IMK. “In the densely populated Germany, framework conditions are much stricter and much more attention is paid to reducing and monitoring emissions.”

Fracking is increasingly discussed as a technology to extract fossil resources from unconventional deposits. Hydraulic breaking of suitable shale stone layers opens up the fossil fuels stored there and makes them accessible for economically efficient use. For this purpose, boreholes are drilled into these rock formations. Then, they are subjected to high pressure using large amounts of water and auxiliary materials, such as sand, cement, and chemicals. The oil or gas can flow to the surface through the opened microstructures in the rock. Typically, the return flow of the aqueous fracking liquid with the dissolved oil and gas constituents to the surface lasts several days until the production phase proper of purer oil or natural gas. This return flow is collected and then reused until it finally has to be disposed of. Air pollution mainly depends on the treatment of this return flow at the extraction plant. In this respect, currently practiced fracking technologies differ considerably. For the first time now, the resulting local atmospheric emissions were studied at a high temporary resolution. Based on the results, emissions can be assigned directly to the different plant sections of an extraction plant. For measurement, the newly developed, compact, and highly sensitive instrument, a so-called proton transfer reaction mass spectrometer (PTR-MS), of KIT was installed on board of a minivan and driven closer to the different extraction points, the distances being a few tens of meters. In this way, the waste gas plumes of individual extraction sources and fracking processes were studied in detail.

Warneke, C., Geiger, F., Edwards, P. M., Dube, W., Pétron, G., Kofler, J., Zahn, A., Brown, S. S., Graus, M., Gilman, J. B., Lerner, B. M., Peischl, J., Ryerson, T. B., de Gouw, J. A., and Roberts, J. M.: Volatile organic compound emissions from the oil and natural gas industry in the Uintah Basin, Utah: oil and gas well pad emissions compared to ambient air composition, Atmos. Chem. Phys., 14, 10977-10988, doi:10.5194/acp-14-10977-2014, 2014.

Antarctica: Heat comes from the deep

The Antarctic ice sheet is a giant water reservoir. The ice cap on the southern continent is on average 2,100 meters thick and contains about 70 percent of the world’s fresh water. If this ice mass were to melt completely, it could raise the global sea level by 60 meters. Therefore scientists carefully observe changes in the Antarctic. In the renowned international journal Science, researchers from Germany, the UK, the US and Japan are now publishing data according to which water temperatures, in particular on the shallow shelf seas of West Antarctica, are rising. “There are many large glaciers in the area. The elevated temperatures have accelerated the melting and sliding of these glaciers in recent decades and there are no indications that this trend is changing,” says the lead author of the study, Dr. Sunke Schmidtko from GEOMAR Helmholtz Centre for Ocean Research Kiel.

For their study, he and his colleagues of the University of East Anglia, the California Institute of Technology and the University of Hokkaido (Japan) evaluated all oceanographic data from the waters around Antarctica from 1960 to 2014 that were available in public databases. These data show that five decades ago, the water masses in the West Antarctic shelf seas were already warmer than in other parts of Antarctica, for example, in the Weddell Sea. However, the temperature difference is not constant. Since 1960, the temperatures in the West Antarctic Amundsen Sea and the Bellingshausen Sea have been rising. “Based on the data we were able to see that this shelf process is induced from the open ocean,” says Dr. Schmidtko.

Around Antarctica in greater depth along the continental slope water masses with temperatures from 0.5 to 1.5°C (33-35°F) are predominant. These temperatures are very warm for Antarctic conditions. “These waters have warmed in West Antarctica over the past 50 years. And they are significant shallower than 50 years ago,” says Schmidtko. Especially in the Amundsen Sea and Bellingshausen Sea they now increasingly spill onto the shelf and warm the shelf.

“These are the regions in which accelerated glacial melting has been observed for some time. We show that oceanographic changes over the past 50 years have probably caused this melting. If the water continues to warm, the increased penetration of warmer water masses onto the shelf will likely further accelerate this process, with an impact on the rate of global sea level rise ” explains Professor Karen Heywood from the University of East Anglia.

The scientists also draw attention to the rising up of warm water masses in the southwestern Weddell Sea. Here very cold temperatures (less than minus 1.5°C or 29°F) prevail on the shelf and a large-scale melting of shelf ice has not been observed yet. If the shoaling of warm water masses continues, it is expected that there will be major environmental changes with dramatic consequences for the Filchner or Ronne Ice Shelf, too. For the first time glaciers outside the West Antarctic could experience enhanced melting from below.

To what extent the diverse biology of the Southern Ocean is influenced by the observed changes is not fully understood. The shelf areas include spawning areas for the Antarctic krill, a shrimp species widespread in the Southern Ocean, which plays a key role in the Antarctic food chain. Research results have shown that spawning cycles could change in warmer conditions. A final assessment of the impact has not yet been made.

The exact reasons for the increase of the heating and the rising of warm water masses has not yet been completely resolved. “We suspect that they are related to large-scale variations in wind systems over the southern hemisphere. But which processes specifically play a role must be evaluated in more detail.” says Dr. Schmidtko.

West Antarctic melt rate has tripled: UC Irvine-NASA

A comprehensive, 21-year analysis of the fastest-melting region of Antarctica has found that the melt rate of glaciers there has tripled during the last decade.

The glaciers in the Amundsen Sea Embayment in West Antarctica are hemorrhaging ice faster than any other part of Antarctica and are the most significant Antarctic contributors to sea level rise. This study is the first to evaluate and reconcile observations from four different measurement techniques to produce an authoritative estimate of the amount and the rate of loss over the last two decades.

“The mass loss of these glaciers is increasing at an amazing rate,” said scientist Isabella Velicogna, jointly of the UC Irvine and NASA’s Jet Propulsion Laboratory. Velicogna is a coauthor of a paper on the results, which has been accepted for Dec. 5 publication in the journal Geophysical Research Letters.

Lead author Tyler Sutterley, a UCI doctoral candidate, and his team did the analysis to verify that the melting in this part of Antarctica is shifting into high gear. “Previous studies had suggested that this region is starting to change very dramatically since the 1990s, and we wanted to see how all the different techniques compared,” Sutterley said. “The remarkable agreement among the techniques gave us confidence that we are getting this right.”

The researchers reconciled measurements of the mass balance of glaciers flowing into the Amundsen Sea Embayment. Mass balance is a measure of how much ice the glaciers gain and lose over time from accumulating or melting snow, discharges of ice as icebergs, and other causes. Measurements from all four techniques were available from 2003 to 2009. Combined, the four data sets span the years 1992 to 2013.

The glaciers in the embayment lost mass throughout the entire period. The researchers calculated two separate quantities: the total amount of loss, and the changes in the rate of loss.

The total amount of loss averaged 83 gigatons per year (91.5 billion U.S. tons). By comparison, Mt. Everest weighs about 161 gigatons, meaning the Antarctic glaciers lost a Mt.-Everest’s-worth amount of water weight every two years over the last 21 years.

The rate of loss accelerated an average of 6.1 gigatons (6.7 billion U.S. tons) per year since 1992.

From 2003 to 2009, when all four observational techniques overlapped, the melt rate increased an average of 16.3 gigatons per year — almost three times the rate of increase for the full 21-year period. The total amount of loss was close to the average at 84 gigatons.

The four sets of observations include NASA’s Gravity Recovery and Climate Experiment (GRACE) satellites, laser altimetry from NASA’s Operation IceBridge airborne campaign and earlier ICESat satellite, radar altimetry from the European Space Agency’s Envisat satellite, and mass budget analyses using radars and the University of Utrecht’s Regional Atmospheric Climate Model.

The scientists noted that glacier and ice sheet behavior worldwide is by far the greatest uncertainty in predicting future sea level. “We have an excellent observing network now. It’s critical that we maintain this network to continue monitoring the changes,” Velicogna said, “because the changes are proceeding very fast.”


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