Glacier beds can get slipperier at higher sliding speeds

Neal Iverson developed the Iowa State University Sliding Simulator to test how glaciers slide over their beds. -  Bob Elbert/Iowa State University
Neal Iverson developed the Iowa State University Sliding Simulator to test how glaciers slide over their beds. – Bob Elbert/Iowa State University

As a glacier’s sliding speed increases, the bed beneath the glacier can grow slipperier, according to laboratory experiments conducted by Iowa State University glaciologists.

They say including this effect in efforts to calculate future increases in glacier speeds could improve predictions of ice volume lost to the oceans and the rate of sea-level rise.

The glaciologists – Lucas Zoet, a postdoctoral research associate, and Neal Iverson, a professor of geological and atmospheric sciences – describe the results of their experiments in the Journal of Glaciology. The paper uses data collected from a newly constructed laboratory tool, the Iowa State University Sliding Simulator, to investigate glacier sliding. The device was used to explore the relationship between drag and sliding speed for comparison with the predictions of theoretical models.

“We really have a unique opportunity to study the base of glaciers with these experiments,” said Zoet, the lead author of the paper. “The other tactic you might take is studying these relationships with field observations, but with field data so many different processes are mixed together that it becomes hard to untangle the relevant data from the noise.”

Data collected by the researchers show that resistance to glacier sliding – the drag that the bed exerts on the ice – can decrease in response to increasing sliding speed. This decrease in drag with increasing speed, although predicted by some theoreticians a long as 45 years ago, is the opposite of what is usually assumed in mathematical models of the flow of ice sheets.

These are the first empirical results demonstrating that as ice slides at an increasing speed – perhaps in response to changing weather or climate – the bed can become slipperier, which could promote still faster glacier flow.

The response of glaciers to changing climate is one of the largest potential contributors to sea-level rise. Predicting glacier response to climate change depends on properly characterizing the way a glacier slides over its bed. There has been a half-century debate among theoreticians as to how to do that.

The simulator features a ring of ice about 8 inches thick and about 3 feet across that is rotated over a model glacier bed. Below the ice is a hydraulic press that can simulate the weight of a glacier several hundred yards thick. Above are motors that can rotate the ice ring over the bed at either a constant speed or a constant stress. A circulating, temperature-regulated fluid keeps the ice at its melting temperature – a necessary condition for significant sliding.

“About six years were required to design, construct, and work the bugs out of the new apparatus,” Iverson said, “but it is performing well now and allowing hypothesis tests that were formerly not possible.”

Glacier beds can get slipperier at higher sliding speeds

Neal Iverson developed the Iowa State University Sliding Simulator to test how glaciers slide over their beds. -  Bob Elbert/Iowa State University
Neal Iverson developed the Iowa State University Sliding Simulator to test how glaciers slide over their beds. – Bob Elbert/Iowa State University

As a glacier’s sliding speed increases, the bed beneath the glacier can grow slipperier, according to laboratory experiments conducted by Iowa State University glaciologists.

They say including this effect in efforts to calculate future increases in glacier speeds could improve predictions of ice volume lost to the oceans and the rate of sea-level rise.

The glaciologists – Lucas Zoet, a postdoctoral research associate, and Neal Iverson, a professor of geological and atmospheric sciences – describe the results of their experiments in the Journal of Glaciology. The paper uses data collected from a newly constructed laboratory tool, the Iowa State University Sliding Simulator, to investigate glacier sliding. The device was used to explore the relationship between drag and sliding speed for comparison with the predictions of theoretical models.

“We really have a unique opportunity to study the base of glaciers with these experiments,” said Zoet, the lead author of the paper. “The other tactic you might take is studying these relationships with field observations, but with field data so many different processes are mixed together that it becomes hard to untangle the relevant data from the noise.”

Data collected by the researchers show that resistance to glacier sliding – the drag that the bed exerts on the ice – can decrease in response to increasing sliding speed. This decrease in drag with increasing speed, although predicted by some theoreticians a long as 45 years ago, is the opposite of what is usually assumed in mathematical models of the flow of ice sheets.

These are the first empirical results demonstrating that as ice slides at an increasing speed – perhaps in response to changing weather or climate – the bed can become slipperier, which could promote still faster glacier flow.

The response of glaciers to changing climate is one of the largest potential contributors to sea-level rise. Predicting glacier response to climate change depends on properly characterizing the way a glacier slides over its bed. There has been a half-century debate among theoreticians as to how to do that.

The simulator features a ring of ice about 8 inches thick and about 3 feet across that is rotated over a model glacier bed. Below the ice is a hydraulic press that can simulate the weight of a glacier several hundred yards thick. Above are motors that can rotate the ice ring over the bed at either a constant speed or a constant stress. A circulating, temperature-regulated fluid keeps the ice at its melting temperature – a necessary condition for significant sliding.

“About six years were required to design, construct, and work the bugs out of the new apparatus,” Iverson said, “but it is performing well now and allowing hypothesis tests that were formerly not possible.”

Hidden movements of Greenland Ice Sheet, runoff revealed

For years NASA has tracked changes in the massive Greenland Ice Sheet. This week scientists using NASA data released the most detailed picture ever of how the ice sheet moves toward the sea and new insights into the hidden plumbing of melt water flowing under the snowy surface.

The results of these studies are expected to improve predictions of the future of the entire Greenland ice sheet and its contribution to sea level rise as researchers revamp their computer models of how the ice sheet reacts to a warming climate.

“With the help of NASA satellite and airborne remote sensing instruments, the Greenland Ice Sheet is finally yielding its secrets,” said Tom Wagner, program scientist for NASA’s cryosphere program in Washington. “These studies represent new leaps in our knowledge of how the ice sheet is losing ice. It turns out the ice sheet is a lot more complex than we ever thought.”

University at Buffalo geophysicist Beata Csatho led an international team that produced the first comprehensive study of how the ice sheet is losing mass based on NASA satellite and airborne data at nearly 100,000 locations across Greenland. The study found that the ice sheet shed about 243 gigatons of ice per year from 2003-09, which agrees with other studies using different techniques. The study was published today in the Proceedings of the National Academy of Sciences.

The study suggests that current ice sheet modeling is too simplistic to accurately predict the future contribution of the Greenland ice sheet to sea level rise, and that current models may underestimate ice loss in the near future.

The project was a massive undertaking, using satellite and aerial data from NASA’s ICESat spacecraft, which measured the elevation of the ice sheet starting in 2003, and the Operation IceBridge field campaign that has flown annually since 2009. Additional airborne data from 1993-2008, collected by NASA’s Program for Arctic Regional Climate Assessment, were also included to extend the timeline of the study.

Current computer simulations of the Greenland Ice Sheet use the activity of four well-studied glaciers — Jakobshavn, Helheim, Kangerlussuaq and Petermann — to forecast how the entire ice sheet will dump ice into the oceans. The new research shows that activity at these four locations may not be representative of what is happening with glaciers across the ice sheet. In fact, glaciers undergo patterns of thinning and thickening that current climate change simulations fail to address, Csatho says.

As a step toward building better models of sea level rise, the research team divided Greenland’s 242 glaciers into 7 major groups based on their behavior from 2003-09.

“Understanding the groupings will help us pick out examples of glaciers that are representative of the whole,” Csatho says. “We can then use data from these representative glaciers in models to provide a more complete picture of what is happening.”

The team also identified areas of rapid shrinkage in southeast Greenland that today’s models don’t acknowledge. This leads Csatho to believe that the ice sheet could lose ice faster in the future than today’s simulations would suggest.

In separate studies presented today at the American Geophysical Union annual meeting in San Francisco, scientists using data from Operation IceBridge found permanent bodies of liquid water in the porous, partially compacted firn layer just below the surface of the ice sheet. Lora Koenig at the National Snow and Ice Data Center in Boulder, Colorado, and Rick Forster at the University of Utah in Salt Lake City, found signatures of near-surface liquid water using ice-penetrating radar.

Across wide areas of Greenland, water can remain liquid, hiding in layers of snow just below the surface, even through cold, harsh winters, researchers are finding. The discoveries by the teams led by Koenig and Forster mean that scientists seeking to understand the future of the Greenland ice sheet need to account for relatively warm liquid water retained in the ice.

Although the total volume of water is small compared to overall melting in Greenland, the presence of liquid water throughout the year could help kick off melt in the spring and summer. “More year-round water means more heat is available to warm the ice,” Koenig said.

Koenig and her colleagues found that sub-surface liquid water are common on the western edges of the Greenland Ice Sheet. At roughly the same time, Forster used similar ground-based radars to find a large aquifer in southeastern Greenland. These studies show that liquid water can persist near the surface around the perimeter of the ice sheet year round.

Another researcher participating in the briefing found that near-surface layers can also contain masses of solid ice that can lead to flooding events. Michael MacFerrin, a scientist at the Cooperative Institute for Research in Environmental Sciences at the University of Colorado Boulder, and colleagues studying radar data from IceBridge and surface based instruments found near surface patches of ice known as ice lenses more than 25 miles farther inland than previously recorded.

Ice lenses form when firn collects surface meltwater like a sponge. When this shallow ice melts, as was seen during July 2012, they can release large amounts of water that can lead to flooding. Warm summers and resulting increased surface melt in recent years have likely caused ice lenses to grow thicker and spread farther inland. “This represents a rapid feedback mechanism. If current trends continue, the flooding will get worse,” MacFerrin said.




Video
Click on this image to view the .mp4 video
This animation (from March 2014) portrays the changes occurring in the surface elevation of the Greenland Ice Sheet since 2003 in three drainage areas: the southeast, the northeast and the Jakobshavn regions. In each region, the time advances to show the accumulated change in elevation, 2003-2012.

Downloadable video: http://svs.gsfc.nasa.gov/cgi-bin/details.cgi?aid=4022 – NASA SVS NASA’s Goddard Space Flight Center

Hidden movements of Greenland Ice Sheet, runoff revealed

For years NASA has tracked changes in the massive Greenland Ice Sheet. This week scientists using NASA data released the most detailed picture ever of how the ice sheet moves toward the sea and new insights into the hidden plumbing of melt water flowing under the snowy surface.

The results of these studies are expected to improve predictions of the future of the entire Greenland ice sheet and its contribution to sea level rise as researchers revamp their computer models of how the ice sheet reacts to a warming climate.

“With the help of NASA satellite and airborne remote sensing instruments, the Greenland Ice Sheet is finally yielding its secrets,” said Tom Wagner, program scientist for NASA’s cryosphere program in Washington. “These studies represent new leaps in our knowledge of how the ice sheet is losing ice. It turns out the ice sheet is a lot more complex than we ever thought.”

University at Buffalo geophysicist Beata Csatho led an international team that produced the first comprehensive study of how the ice sheet is losing mass based on NASA satellite and airborne data at nearly 100,000 locations across Greenland. The study found that the ice sheet shed about 243 gigatons of ice per year from 2003-09, which agrees with other studies using different techniques. The study was published today in the Proceedings of the National Academy of Sciences.

The study suggests that current ice sheet modeling is too simplistic to accurately predict the future contribution of the Greenland ice sheet to sea level rise, and that current models may underestimate ice loss in the near future.

The project was a massive undertaking, using satellite and aerial data from NASA’s ICESat spacecraft, which measured the elevation of the ice sheet starting in 2003, and the Operation IceBridge field campaign that has flown annually since 2009. Additional airborne data from 1993-2008, collected by NASA’s Program for Arctic Regional Climate Assessment, were also included to extend the timeline of the study.

Current computer simulations of the Greenland Ice Sheet use the activity of four well-studied glaciers — Jakobshavn, Helheim, Kangerlussuaq and Petermann — to forecast how the entire ice sheet will dump ice into the oceans. The new research shows that activity at these four locations may not be representative of what is happening with glaciers across the ice sheet. In fact, glaciers undergo patterns of thinning and thickening that current climate change simulations fail to address, Csatho says.

As a step toward building better models of sea level rise, the research team divided Greenland’s 242 glaciers into 7 major groups based on their behavior from 2003-09.

“Understanding the groupings will help us pick out examples of glaciers that are representative of the whole,” Csatho says. “We can then use data from these representative glaciers in models to provide a more complete picture of what is happening.”

The team also identified areas of rapid shrinkage in southeast Greenland that today’s models don’t acknowledge. This leads Csatho to believe that the ice sheet could lose ice faster in the future than today’s simulations would suggest.

In separate studies presented today at the American Geophysical Union annual meeting in San Francisco, scientists using data from Operation IceBridge found permanent bodies of liquid water in the porous, partially compacted firn layer just below the surface of the ice sheet. Lora Koenig at the National Snow and Ice Data Center in Boulder, Colorado, and Rick Forster at the University of Utah in Salt Lake City, found signatures of near-surface liquid water using ice-penetrating radar.

Across wide areas of Greenland, water can remain liquid, hiding in layers of snow just below the surface, even through cold, harsh winters, researchers are finding. The discoveries by the teams led by Koenig and Forster mean that scientists seeking to understand the future of the Greenland ice sheet need to account for relatively warm liquid water retained in the ice.

Although the total volume of water is small compared to overall melting in Greenland, the presence of liquid water throughout the year could help kick off melt in the spring and summer. “More year-round water means more heat is available to warm the ice,” Koenig said.

Koenig and her colleagues found that sub-surface liquid water are common on the western edges of the Greenland Ice Sheet. At roughly the same time, Forster used similar ground-based radars to find a large aquifer in southeastern Greenland. These studies show that liquid water can persist near the surface around the perimeter of the ice sheet year round.

Another researcher participating in the briefing found that near-surface layers can also contain masses of solid ice that can lead to flooding events. Michael MacFerrin, a scientist at the Cooperative Institute for Research in Environmental Sciences at the University of Colorado Boulder, and colleagues studying radar data from IceBridge and surface based instruments found near surface patches of ice known as ice lenses more than 25 miles farther inland than previously recorded.

Ice lenses form when firn collects surface meltwater like a sponge. When this shallow ice melts, as was seen during July 2012, they can release large amounts of water that can lead to flooding. Warm summers and resulting increased surface melt in recent years have likely caused ice lenses to grow thicker and spread farther inland. “This represents a rapid feedback mechanism. If current trends continue, the flooding will get worse,” MacFerrin said.




Video
Click on this image to view the .mp4 video
This animation (from March 2014) portrays the changes occurring in the surface elevation of the Greenland Ice Sheet since 2003 in three drainage areas: the southeast, the northeast and the Jakobshavn regions. In each region, the time advances to show the accumulated change in elevation, 2003-2012.

Downloadable video: http://svs.gsfc.nasa.gov/cgi-bin/details.cgi?aid=4022 – NASA SVS NASA’s Goddard Space Flight Center

Research links soil mineral surfaces to key atmospheric processes

Pictured are, from left, are David Bish, Melissa Donaldson and Jonathan Raff. -  Indiana University
Pictured are, from left, are David Bish, Melissa Donaldson and Jonathan Raff. – Indiana University

Research by Indiana University scientists finds that soil may be a significant and underappreciated source of nitrous acid, a chemical that plays a pivotal role in atmospheric processes such as the formation of smog and determining the lifetime of greenhouse gases.

The study shows for the first time that the surface acidity of common minerals found in soil determines whether the gas nitrous acid will be released into the atmosphere. The finding could contribute to improved models for understanding and controlling air pollution, a significant public health concern.

“We find that the surfaces of minerals in the soil can be much more acidic than the overall pH of the soil would suggest,” said Jonathan Raff, assistant professor in the School of Public and Environmental Affairs and Department of Chemistry. “It’s the acidity of the soil minerals that acts as a knob or a control lever, and that determines whether nitrous acid outgasses from soil or remains as nitrite.”

The article, “Soil surface acidity plays a determining role in the atmospheric-terrestrial exchange of nitrous acid,” will be published this week in the journal Proceedings of the National Academy of Sciences. Melissa A. Donaldson, a Ph.D. student in the School of Public and Environmental Affairs, is the lead author. Co-authors are Raff and David L. Bish, the Haydn Murray Chair of Applied Clay Mineralogy in the Department of Geological Sciences.

Nitrous acid, or HONO, plays a key role in regulating atmospheric processes. Sunlight causes it to break down into nitric oxide and the hydroxyl radical, OH. The latter controls the atmospheric lifetime of gases important to air quality and climate change and initiates the chemistry leading to the formation of ground-level ozone, a primary component of smog.

Scientists have known about the nitrous acid’s role in air pollution for 40 years, but they haven’t fully understood how it is produced and destroyed or how it interacts with other substances, because HONO is unstable and difficult to measure.

“Only in the last 10 years have we had the technology to study nitrous acid under environmentally relevant conditions,” Raff said.

Recent studies have shown nitrous acid to be emitted from soil in many locations. But this was unexpected because, according to basic chemistry, the reactions that release nitrous acid should take place only in extremely acidic soils, typically found in rain forests or the taiga of North America and Eurasia.

The standard method to determine the acidity of soil is to mix bulk soil with water and measure the overall pH. But the IU researchers show that the crucial factor is not overall pH but the acidity at the surface of soil minerals, especially iron oxides and aluminum oxides. At the molecular level, the water adsorbed directly to these minerals is unusually acidic and facilitates the conversion of nitrite in the soil to nitrous acid, which then volatilizes.

“With the traditional approach of calculating soil pH, we were severely underestimating nitrous acid emissions from soil,” Raff said. “I think the source is going to turn out to be more important than was previously imagined.”

The research was carried out using soil from a farm field near Columbus, Ind. But aluminum and iron oxides are ubiquitous in soil, and the researchers say the results suggest that about 70 percent of Earth’s soils could be sources of nitrous acid.

Ultimately, the research will contribute to a better understanding of how nitrous acid is produced and how it affects atmospheric processes. That in turn will improve the computer models used by the U.S. Environmental Protection Agency and other regulatory agencies to control air pollution, which the World Health Organization estimates contributes to 7 million premature deaths annually.

“With improved models, policymakers can make better judgments about the costs and benefits of regulations,” Raff said. “If we don’t get the chemistry right, we’re not going to get the right answers to our policy questions regarding air pollution.”

Research links soil mineral surfaces to key atmospheric processes

Pictured are, from left, are David Bish, Melissa Donaldson and Jonathan Raff. -  Indiana University
Pictured are, from left, are David Bish, Melissa Donaldson and Jonathan Raff. – Indiana University

Research by Indiana University scientists finds that soil may be a significant and underappreciated source of nitrous acid, a chemical that plays a pivotal role in atmospheric processes such as the formation of smog and determining the lifetime of greenhouse gases.

The study shows for the first time that the surface acidity of common minerals found in soil determines whether the gas nitrous acid will be released into the atmosphere. The finding could contribute to improved models for understanding and controlling air pollution, a significant public health concern.

“We find that the surfaces of minerals in the soil can be much more acidic than the overall pH of the soil would suggest,” said Jonathan Raff, assistant professor in the School of Public and Environmental Affairs and Department of Chemistry. “It’s the acidity of the soil minerals that acts as a knob or a control lever, and that determines whether nitrous acid outgasses from soil or remains as nitrite.”

The article, “Soil surface acidity plays a determining role in the atmospheric-terrestrial exchange of nitrous acid,” will be published this week in the journal Proceedings of the National Academy of Sciences. Melissa A. Donaldson, a Ph.D. student in the School of Public and Environmental Affairs, is the lead author. Co-authors are Raff and David L. Bish, the Haydn Murray Chair of Applied Clay Mineralogy in the Department of Geological Sciences.

Nitrous acid, or HONO, plays a key role in regulating atmospheric processes. Sunlight causes it to break down into nitric oxide and the hydroxyl radical, OH. The latter controls the atmospheric lifetime of gases important to air quality and climate change and initiates the chemistry leading to the formation of ground-level ozone, a primary component of smog.

Scientists have known about the nitrous acid’s role in air pollution for 40 years, but they haven’t fully understood how it is produced and destroyed or how it interacts with other substances, because HONO is unstable and difficult to measure.

“Only in the last 10 years have we had the technology to study nitrous acid under environmentally relevant conditions,” Raff said.

Recent studies have shown nitrous acid to be emitted from soil in many locations. But this was unexpected because, according to basic chemistry, the reactions that release nitrous acid should take place only in extremely acidic soils, typically found in rain forests or the taiga of North America and Eurasia.

The standard method to determine the acidity of soil is to mix bulk soil with water and measure the overall pH. But the IU researchers show that the crucial factor is not overall pH but the acidity at the surface of soil minerals, especially iron oxides and aluminum oxides. At the molecular level, the water adsorbed directly to these minerals is unusually acidic and facilitates the conversion of nitrite in the soil to nitrous acid, which then volatilizes.

“With the traditional approach of calculating soil pH, we were severely underestimating nitrous acid emissions from soil,” Raff said. “I think the source is going to turn out to be more important than was previously imagined.”

The research was carried out using soil from a farm field near Columbus, Ind. But aluminum and iron oxides are ubiquitous in soil, and the researchers say the results suggest that about 70 percent of Earth’s soils could be sources of nitrous acid.

Ultimately, the research will contribute to a better understanding of how nitrous acid is produced and how it affects atmospheric processes. That in turn will improve the computer models used by the U.S. Environmental Protection Agency and other regulatory agencies to control air pollution, which the World Health Organization estimates contributes to 7 million premature deaths annually.

“With improved models, policymakers can make better judgments about the costs and benefits of regulations,” Raff said. “If we don’t get the chemistry right, we’re not going to get the right answers to our policy questions regarding air pollution.”

New study measures methane emissions from natural gas production and offers insights into 2 large sources

A team of researchers from the Cockrell School of Engineering at The University of Texas at Austin and environmental testing firm URS reports that a small subset of natural gas wells are responsible for the majority of methane emissions from two major sources — liquid unloadings and pneumatic controller equipment — at natural gas production sites.

With natural gas production in the United States expected to continue to increase during the next few decades, there is a need for a better understanding of methane emissions during natural gas production. The study team believes this research, published Dec. 9 in Environmental Science & Technology, will help to provide a clearer picture of methane emissions from natural gas production sites.

The UT Austin-led field study closely examined two major sources of methane emissions — liquid unloadings and pneumatic controller equipment — at well pad sites across the United States. Researchers found that 19 percent of the pneumatic devices accounted for 95 percent of the emissions from pneumatic devices, and 20 percent of the wells with unloading emissions that vent to the atmosphere accounted for 65 percent to 83 percent of those emissions.

“To put this in perspective, over the past several decades, 10 percent of the cars on the road have been responsible for the majority of automotive exhaust pollution,” said David Allen, chemical engineering professor at the Cockrell School and principal investigator for the study. “Similarly, a small group of sources within these two categories are responsible for the vast majority of pneumatic and unloading emissions at natural gas production sites.”

Additionally, for pneumatic devices, the study confirmed regional differences in methane emissions first reported by the study team in 2013. The researchers found that methane emissions from pneumatic devices were highest in the Gulf Coast and lowest in the Rocky Mountains.

The study is the second phase of the team’s 2013 study, which included some of the first measurements for methane emissions taken directly at hydraulically fractured well sites. Both phases of the study involved a partnership between the Environmental Defense Fund, participating energy companies, an independent Scientific Advisory Panel and the UT Austin study team.

The unprecedented access to natural gas production facilities and equipment allowed researchers to acquire direct measurements of methane emissions.

Study and Findings on Pneumatic Devices

Pneumatic devices, which use gas pressure to control the opening and closing of valves, emit gas as they operate. These emissions are estimated to be among the larger sources of methane emissions from the natural gas supply chain. The Environmental Protection Agency reports that 477,606 pneumatic (gas actuated) devices are in use at natural gas production sites throughout the U.S.

“Our team’s previous work established that pneumatics are a major contributor to emissions,” Allen said. “Our goal here was to measure a more diverse population of wells to characterize the features of high-emitting pneumatic controllers.”

The research team measured emissions from 377 gas actuated (pneumatic) controllers at natural gas production sites and a small number of oil production sites throughout the U.S.

The researchers sampled all identifiable pneumatic controller devices at each well site, a more comprehensive approach than the random sampling previously conducted. The average methane emissions per pneumatic controller reported in this study are 17 percent higher than the average emissions per pneumatic controller in the 2012 EPA greenhouse gas national emission inventory (released in 2014), but the average from the study is dominated by a small subpopulation of the controllers. Specifically, 19 percent of controllers, with measured emission rates in excess of 6 standard cubic feet per hour (scf/h), accounted for 95 percent of emissions.

The high-emitting pneumatic devices are a combination of devices that are not operating as designed, are used in applications that cause them to release gas frequently or are designed to emit continuously at a high rate.

The researchers also observed regional differences in methane emission levels, with the lowest emissions per device measured in the Rocky Mountains and the highest emissions in the Gulf Coast, similar to the earlier 2013 study. At least some of the regional differences in emission rates can be attributed to the difference in controller type (continuous vent vs. intermittent vent) among regions.

Study and Findings on Liquid Unloadings

After observing variable emissions for liquid unloadings for a limited group of well types in the 2013 study, the research team made more extensive measurements and confirmed that a majority of emissions come from a small fraction of wells that vent frequently. Although it is not surprising to see some correlation between frequency of unloadings and higher annual emissions, the study’s findings indicate that wells with a high frequency of unloadings have annual emissions that are 10 or more times as great as wells that unload less frequently.

The team’s field study, which measured emissions from unloadings from wells at 107 natural gas production wells throughout the U.S., represents the most extensive measurement of emissions associated with liquid unloadings in scientific literature thus far.

A liquid unloading is one method used to clear wells of accumulated liquids to increase production. Because older wells typically produce less gas as they near the end of their life cycle, liquid unloadings happen more often in those wells than in newer wells. The team found a statistical correlation between the age of wells and the frequency of liquid unloadings. The researchers found that the key identifier for high-emitting wells is how many times the well unloads in a given year.

Because liquid unloadings can employ a variety of liquid lifting mechanisms, the study results also reflect differences in liquid unloadings emissions between wells that use two different mechanisms (wells with plunger lifts and wells without plunger lifts). Emissions for unloading events for wells without plunger lifts averaged 21,000 scf (standard cubic feet) to 35,000 scf. For wells with plunger lifts that vent to the atmosphere, emissions averaged 1,000 scf to 10,000 scf of methane per event. Although the emissions per event were higher for wells without plunger lifts, these wells had, on average, fewer events than wells with plunger lifts. Wells without plunger lifts averaged fewer than 10 unloading events per year, and wells with plunger lifts averaged more than 200 events per year.Overall, wells with plunger lifts were estimated to account for 70 percent of emissions from unloadings nationally.

Additionally, researchers found that the Rocky Mountain region, with its large number of wells with a high frequency of unloadings that vent to the atmosphere, accounts for about half of overall emissions from liquid unloadings.

The study team hopes its measurements of liquid unloadings and pneumatic devices will provide a clearer picture of methane emissions from natural gas well sites and about the relationship between well characteristics and emissions.

The study was a cooperative effort involving experts from the Environmental Defense Fund, Anadarko Petroleum Corporation, BG Group PLC, Chevron, ConocoPhillips, Encana Oil & Gas (USA) Inc., Pioneer Natural Resources Company, SWEPI LP (Shell), Statoil, Southwestern Energy and XTO Energy, a subsidiary of ExxonMobil.

The University of Texas at Austin is committed to transparency and disclosure of all potential conflicts of interest of its researchers. Lead researcher David Allen serves as chair of the Environmental Protection Agency’s Science Advisory Board and in this role is a paid Special Governmental Employee. He is also a journal editor for the American Chemical Society and has served as a consultant for multiple companies, including Eastern Research Group, ExxonMobil and the Research Triangle Institute. He has worked on other research projects funded by a variety of governmental, nonprofit and private sector sources including the National Science Foundation, the Environmental Protection Agency, the Texas Commission on Environmental Quality, the American Petroleum Institute and an air monitoring and surveillance project that was ordered by the U.S. District Court for the Southern District of Texas. Adam Pacsi and Daniel Zavala-Araiza, who were graduate students at The University of Texas at the time this work was done, have accepted positions at Chevron Energy Technology Company and the Environmental Defense Fund, respectively.

Financial support for this work was provided by the Environmental Defense Fund (EDF), Anadarko Petroleum Corporation, BG Group PLC, Chevron, ConocoPhillips, Encana Oil & Gas (USA) Inc., Pioneer Natural Resources Company, SWEPI LP (Shell), Statoil, Southwestern Energy and XTO Energy, a subsidiary of ExxonMobil.

Major funding for the EDF’s 30-month methane research series, including their portion of the University of Texas study, is provided for by the following individuals and foundations: Fiona and Stan Druckenmiller, the Heising-Simons Foundation, Bill and Susan Oberndorf, Betsy and Sam Reeves, the Robertson Foundation, TomKat Charitable Trust and the Walton Family Foundation.

New study measures methane emissions from natural gas production and offers insights into 2 large sources

A team of researchers from the Cockrell School of Engineering at The University of Texas at Austin and environmental testing firm URS reports that a small subset of natural gas wells are responsible for the majority of methane emissions from two major sources — liquid unloadings and pneumatic controller equipment — at natural gas production sites.

With natural gas production in the United States expected to continue to increase during the next few decades, there is a need for a better understanding of methane emissions during natural gas production. The study team believes this research, published Dec. 9 in Environmental Science & Technology, will help to provide a clearer picture of methane emissions from natural gas production sites.

The UT Austin-led field study closely examined two major sources of methane emissions — liquid unloadings and pneumatic controller equipment — at well pad sites across the United States. Researchers found that 19 percent of the pneumatic devices accounted for 95 percent of the emissions from pneumatic devices, and 20 percent of the wells with unloading emissions that vent to the atmosphere accounted for 65 percent to 83 percent of those emissions.

“To put this in perspective, over the past several decades, 10 percent of the cars on the road have been responsible for the majority of automotive exhaust pollution,” said David Allen, chemical engineering professor at the Cockrell School and principal investigator for the study. “Similarly, a small group of sources within these two categories are responsible for the vast majority of pneumatic and unloading emissions at natural gas production sites.”

Additionally, for pneumatic devices, the study confirmed regional differences in methane emissions first reported by the study team in 2013. The researchers found that methane emissions from pneumatic devices were highest in the Gulf Coast and lowest in the Rocky Mountains.

The study is the second phase of the team’s 2013 study, which included some of the first measurements for methane emissions taken directly at hydraulically fractured well sites. Both phases of the study involved a partnership between the Environmental Defense Fund, participating energy companies, an independent Scientific Advisory Panel and the UT Austin study team.

The unprecedented access to natural gas production facilities and equipment allowed researchers to acquire direct measurements of methane emissions.

Study and Findings on Pneumatic Devices

Pneumatic devices, which use gas pressure to control the opening and closing of valves, emit gas as they operate. These emissions are estimated to be among the larger sources of methane emissions from the natural gas supply chain. The Environmental Protection Agency reports that 477,606 pneumatic (gas actuated) devices are in use at natural gas production sites throughout the U.S.

“Our team’s previous work established that pneumatics are a major contributor to emissions,” Allen said. “Our goal here was to measure a more diverse population of wells to characterize the features of high-emitting pneumatic controllers.”

The research team measured emissions from 377 gas actuated (pneumatic) controllers at natural gas production sites and a small number of oil production sites throughout the U.S.

The researchers sampled all identifiable pneumatic controller devices at each well site, a more comprehensive approach than the random sampling previously conducted. The average methane emissions per pneumatic controller reported in this study are 17 percent higher than the average emissions per pneumatic controller in the 2012 EPA greenhouse gas national emission inventory (released in 2014), but the average from the study is dominated by a small subpopulation of the controllers. Specifically, 19 percent of controllers, with measured emission rates in excess of 6 standard cubic feet per hour (scf/h), accounted for 95 percent of emissions.

The high-emitting pneumatic devices are a combination of devices that are not operating as designed, are used in applications that cause them to release gas frequently or are designed to emit continuously at a high rate.

The researchers also observed regional differences in methane emission levels, with the lowest emissions per device measured in the Rocky Mountains and the highest emissions in the Gulf Coast, similar to the earlier 2013 study. At least some of the regional differences in emission rates can be attributed to the difference in controller type (continuous vent vs. intermittent vent) among regions.

Study and Findings on Liquid Unloadings

After observing variable emissions for liquid unloadings for a limited group of well types in the 2013 study, the research team made more extensive measurements and confirmed that a majority of emissions come from a small fraction of wells that vent frequently. Although it is not surprising to see some correlation between frequency of unloadings and higher annual emissions, the study’s findings indicate that wells with a high frequency of unloadings have annual emissions that are 10 or more times as great as wells that unload less frequently.

The team’s field study, which measured emissions from unloadings from wells at 107 natural gas production wells throughout the U.S., represents the most extensive measurement of emissions associated with liquid unloadings in scientific literature thus far.

A liquid unloading is one method used to clear wells of accumulated liquids to increase production. Because older wells typically produce less gas as they near the end of their life cycle, liquid unloadings happen more often in those wells than in newer wells. The team found a statistical correlation between the age of wells and the frequency of liquid unloadings. The researchers found that the key identifier for high-emitting wells is how many times the well unloads in a given year.

Because liquid unloadings can employ a variety of liquid lifting mechanisms, the study results also reflect differences in liquid unloadings emissions between wells that use two different mechanisms (wells with plunger lifts and wells without plunger lifts). Emissions for unloading events for wells without plunger lifts averaged 21,000 scf (standard cubic feet) to 35,000 scf. For wells with plunger lifts that vent to the atmosphere, emissions averaged 1,000 scf to 10,000 scf of methane per event. Although the emissions per event were higher for wells without plunger lifts, these wells had, on average, fewer events than wells with plunger lifts. Wells without plunger lifts averaged fewer than 10 unloading events per year, and wells with plunger lifts averaged more than 200 events per year.Overall, wells with plunger lifts were estimated to account for 70 percent of emissions from unloadings nationally.

Additionally, researchers found that the Rocky Mountain region, with its large number of wells with a high frequency of unloadings that vent to the atmosphere, accounts for about half of overall emissions from liquid unloadings.

The study team hopes its measurements of liquid unloadings and pneumatic devices will provide a clearer picture of methane emissions from natural gas well sites and about the relationship between well characteristics and emissions.

The study was a cooperative effort involving experts from the Environmental Defense Fund, Anadarko Petroleum Corporation, BG Group PLC, Chevron, ConocoPhillips, Encana Oil & Gas (USA) Inc., Pioneer Natural Resources Company, SWEPI LP (Shell), Statoil, Southwestern Energy and XTO Energy, a subsidiary of ExxonMobil.

The University of Texas at Austin is committed to transparency and disclosure of all potential conflicts of interest of its researchers. Lead researcher David Allen serves as chair of the Environmental Protection Agency’s Science Advisory Board and in this role is a paid Special Governmental Employee. He is also a journal editor for the American Chemical Society and has served as a consultant for multiple companies, including Eastern Research Group, ExxonMobil and the Research Triangle Institute. He has worked on other research projects funded by a variety of governmental, nonprofit and private sector sources including the National Science Foundation, the Environmental Protection Agency, the Texas Commission on Environmental Quality, the American Petroleum Institute and an air monitoring and surveillance project that was ordered by the U.S. District Court for the Southern District of Texas. Adam Pacsi and Daniel Zavala-Araiza, who were graduate students at The University of Texas at the time this work was done, have accepted positions at Chevron Energy Technology Company and the Environmental Defense Fund, respectively.

Financial support for this work was provided by the Environmental Defense Fund (EDF), Anadarko Petroleum Corporation, BG Group PLC, Chevron, ConocoPhillips, Encana Oil & Gas (USA) Inc., Pioneer Natural Resources Company, SWEPI LP (Shell), Statoil, Southwestern Energy and XTO Energy, a subsidiary of ExxonMobil.

Major funding for the EDF’s 30-month methane research series, including their portion of the University of Texas study, is provided for by the following individuals and foundations: Fiona and Stan Druckenmiller, the Heising-Simons Foundation, Bill and Susan Oberndorf, Betsy and Sam Reeves, the Robertson Foundation, TomKat Charitable Trust and the Walton Family Foundation.

No laughing matter: Nitrous oxide rose at end of last ice age

Researchers measured increases in atmospheric nitrous oxide concentrations about 16,000 to 10,000 years ago using ice from Taylor Glacier in Antarctica. -  Adrian Schilt
Researchers measured increases in atmospheric nitrous oxide concentrations about 16,000 to 10,000 years ago using ice from Taylor Glacier in Antarctica. – Adrian Schilt

Nitrous oxide (N2O) is an important greenhouse gas that doesn’t receive as much notoriety as carbon dioxide or methane, but a new study confirms that atmospheric levels of N2O rose significantly as the Earth came out of the last ice age and addresses the cause.

An international team of scientists analyzed air extracted from bubbles enclosed in ancient polar ice from Taylor Glacier in Antarctica, allowing for the reconstruction of the past atmospheric composition. The analysis documented a 30 percent increase in atmospheric nitrous oxide concentrations from 16,000 years ago to 10,000 years ago. This rise in N2O was caused by changes in environmental conditions in the ocean and on land, scientists say, and contributed to the warming at the end of the ice age and the melting of large ice sheets that then existed.

The findings add an important new element to studies of how Earth may respond to a warming climate in the future. Results of the study, which was funded by the U.S. National Science Foundation and the Swiss National Science Foundation, are being published this week in the journal Nature.

“We found that marine and terrestrial sources contributed about equally to the overall increase of nitrous oxide concentrations and generally evolved in parallel at the end of the last ice age,” said lead author Adrian Schilt, who did much of the work as a post-doctoral researcher at Oregon State University. Schilt then continued to work on the study at the Oeschger Centre for Climate Change Research at the University of Bern in Switzerland.

“The end of the last ice age represents a partial analog to modern warming and allows us to study the response of natural nitrous oxide emissions to changing environmental conditions,” Schilt added. “This will allow us to better understand what might happen in the future.”

Nitrous oxide is perhaps best known as laughing gas, but it is also produced by microbes on land and in the ocean in processes that occur naturally, but can be enhanced by human activity. Marine nitrous oxide production is linked closely to low oxygen conditions in the upper ocean and global warming is predicted to intensify the low-oxygen zones in many of the world’s ocean basins. N2O also destroys ozone in the stratosphere.

“Warming makes terrestrial microbes produce more nitrous oxide,” noted co-author Edward Brook, an Oregon State paleoclimatologist whose research team included Schilt. “Greenhouse gases go up and down over time, and we’d like to know more about why that happens and how it affects climate.”

Nitrous oxide is among the most difficult greenhouse gases to study in attempting to reconstruct the Earth’s climate history through ice core analysis. The specific technique that the Oregon State research team used requires large samples of pristine ice that date back to the desired time of study – in this case, between about 16,000 and 10,000 years ago.

The unusual way in which Taylor Glacier is configured allowed the scientists to extract ice samples from the surface of the glacier instead of drilling deep in the polar ice cap because older ice is transported upward near the glacier margins, said Brook, a professor in Oregon State’s College of Earth, Ocean, and Atmospheric Sciences.

The scientists were able to discern the contributions of marine and terrestrial nitrous oxide through analysis of isotopic ratios, which fingerprint the different sources of N2O in the atmosphere.

“The scientific community knew roughly what the N2O concentration trends were prior to this study,” Brook said, “but these findings confirm that and provide more exact details about changes in sources. As nitrous oxide in the atmosphere continues to increase – along with carbon dioxide and methane – we now will be able to more accurately assess where those contributions are coming from and the rate of the increase.”

Atmospheric N2O was roughly 200 parts per billion at the peak of the ice age about 20,000 years ago then rose to 260 ppb by 10,000 years ago. As of 2014, atmospheric N2Owas measured at about 327 ppb, an increase attributed primarily to agricultural influences.

Although the N2O increase at the end of the last ice age was almost equally attributable to marine and terrestrial sources, the scientists say, there were some differences.

“Our data showed that terrestrial emissions changed faster than marine emissions, which was highlighted by a fast increase of emissions on land that preceded the increase in marine emissions,” Schilt pointed out. “It appears to be a direct response to a rapid temperature change between 15,000 and 14,000 years ago.”

That finding underscores the complexity of analyzing how Earth responds to changing conditions that have to account for marine and terrestrial influences; natural variability; the influence of different greenhouse gases; and a host of other factors, Brook said.

“Natural sources of N2O are predicted to increase in the future and this study will help up test predictions on how the Earth will respond,” Brook said.

No laughing matter: Nitrous oxide rose at end of last ice age

Researchers measured increases in atmospheric nitrous oxide concentrations about 16,000 to 10,000 years ago using ice from Taylor Glacier in Antarctica. -  Adrian Schilt
Researchers measured increases in atmospheric nitrous oxide concentrations about 16,000 to 10,000 years ago using ice from Taylor Glacier in Antarctica. – Adrian Schilt

Nitrous oxide (N2O) is an important greenhouse gas that doesn’t receive as much notoriety as carbon dioxide or methane, but a new study confirms that atmospheric levels of N2O rose significantly as the Earth came out of the last ice age and addresses the cause.

An international team of scientists analyzed air extracted from bubbles enclosed in ancient polar ice from Taylor Glacier in Antarctica, allowing for the reconstruction of the past atmospheric composition. The analysis documented a 30 percent increase in atmospheric nitrous oxide concentrations from 16,000 years ago to 10,000 years ago. This rise in N2O was caused by changes in environmental conditions in the ocean and on land, scientists say, and contributed to the warming at the end of the ice age and the melting of large ice sheets that then existed.

The findings add an important new element to studies of how Earth may respond to a warming climate in the future. Results of the study, which was funded by the U.S. National Science Foundation and the Swiss National Science Foundation, are being published this week in the journal Nature.

“We found that marine and terrestrial sources contributed about equally to the overall increase of nitrous oxide concentrations and generally evolved in parallel at the end of the last ice age,” said lead author Adrian Schilt, who did much of the work as a post-doctoral researcher at Oregon State University. Schilt then continued to work on the study at the Oeschger Centre for Climate Change Research at the University of Bern in Switzerland.

“The end of the last ice age represents a partial analog to modern warming and allows us to study the response of natural nitrous oxide emissions to changing environmental conditions,” Schilt added. “This will allow us to better understand what might happen in the future.”

Nitrous oxide is perhaps best known as laughing gas, but it is also produced by microbes on land and in the ocean in processes that occur naturally, but can be enhanced by human activity. Marine nitrous oxide production is linked closely to low oxygen conditions in the upper ocean and global warming is predicted to intensify the low-oxygen zones in many of the world’s ocean basins. N2O also destroys ozone in the stratosphere.

“Warming makes terrestrial microbes produce more nitrous oxide,” noted co-author Edward Brook, an Oregon State paleoclimatologist whose research team included Schilt. “Greenhouse gases go up and down over time, and we’d like to know more about why that happens and how it affects climate.”

Nitrous oxide is among the most difficult greenhouse gases to study in attempting to reconstruct the Earth’s climate history through ice core analysis. The specific technique that the Oregon State research team used requires large samples of pristine ice that date back to the desired time of study – in this case, between about 16,000 and 10,000 years ago.

The unusual way in which Taylor Glacier is configured allowed the scientists to extract ice samples from the surface of the glacier instead of drilling deep in the polar ice cap because older ice is transported upward near the glacier margins, said Brook, a professor in Oregon State’s College of Earth, Ocean, and Atmospheric Sciences.

The scientists were able to discern the contributions of marine and terrestrial nitrous oxide through analysis of isotopic ratios, which fingerprint the different sources of N2O in the atmosphere.

“The scientific community knew roughly what the N2O concentration trends were prior to this study,” Brook said, “but these findings confirm that and provide more exact details about changes in sources. As nitrous oxide in the atmosphere continues to increase – along with carbon dioxide and methane – we now will be able to more accurately assess where those contributions are coming from and the rate of the increase.”

Atmospheric N2O was roughly 200 parts per billion at the peak of the ice age about 20,000 years ago then rose to 260 ppb by 10,000 years ago. As of 2014, atmospheric N2Owas measured at about 327 ppb, an increase attributed primarily to agricultural influences.

Although the N2O increase at the end of the last ice age was almost equally attributable to marine and terrestrial sources, the scientists say, there were some differences.

“Our data showed that terrestrial emissions changed faster than marine emissions, which was highlighted by a fast increase of emissions on land that preceded the increase in marine emissions,” Schilt pointed out. “It appears to be a direct response to a rapid temperature change between 15,000 and 14,000 years ago.”

That finding underscores the complexity of analyzing how Earth responds to changing conditions that have to account for marine and terrestrial influences; natural variability; the influence of different greenhouse gases; and a host of other factors, Brook said.

“Natural sources of N2O are predicted to increase in the future and this study will help up test predictions on how the Earth will respond,” Brook said.